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Marvel’s Avengers: Infinity War - The Beginning of the End
Widow is great as a foil character, especially to Steve Rogers. I loved their interactions in Winter Soldier. I am not sure if there's enough there for her to be the lead character in her own movie, though.
Hawkeye, really, doesn't contribute much. He's the least useful of the Avengers, but at least he knows it and seems to have fun with it.
Black Widow was a very underwritten character. She's basically just a tough chick, the ultimate assassin, without much of a personality or motive. Take the Plinkett test for Black Widow and see what you most remember about her:
They could redeem the character in a solo movie. That's a given.